WEBVTT 00:00:07.042 --> 00:00:10.683 In a time-lapse video, it looks like a monster coming alive. 00:00:10.707 --> 00:00:13.595 For a moment, it sits there innocuously. 00:00:13.619 --> 00:00:16.172 Then, ripples move across its surface. 00:00:16.196 --> 00:00:19.563 It bulges outwards, bursting with weird boils. 00:00:19.587 --> 00:00:21.195 It triples in volume. 00:00:21.219 --> 00:00:24.772 Its color darkens ominously, and its surface hardens 00:00:24.796 --> 00:00:28.777 into an alien topography of peaks and craters. 00:00:28.801 --> 00:00:30.741 Then, the kitchen timer dings. 00:00:30.765 --> 00:00:32.116 Your cookie is ready. 00:00:32.141 --> 00:00:33.904 What happened inside that oven? 00:00:33.928 --> 00:00:35.817 Don't let the apron deceive you! 00:00:35.841 --> 00:00:38.205 Bakers are mad scientists. 00:00:38.229 --> 00:00:40.040 When you slide the pan into the oven, 00:00:40.064 --> 00:00:42.589 you're setting off a series of chemical reactions 00:00:42.613 --> 00:00:47.344 that transform one substance, dough, into another, cookies. 00:00:47.368 --> 00:00:50.289 When the dough reaches 92 degrees Fahrenheit, 00:00:50.313 --> 00:00:51.768 the butter inside melts, 00:00:51.792 --> 00:00:54.017 causing the dough to start spreading out. 00:00:54.041 --> 00:00:55.518 Butter is an emulsion, 00:00:55.542 --> 00:00:57.107 or mixture of two substances 00:00:57.131 --> 00:00:58.985 that don't want to stay together, 00:00:59.009 --> 00:01:01.014 in this case, water and fat, 00:01:01.038 --> 00:01:04.188 along with some dairy solids that help hold them together. 00:01:04.212 --> 00:01:07.400 As the butter melts, its trapped water is released. 00:01:07.424 --> 00:01:10.695 And as the cookie gets hotter, the water expands into steam. 00:01:10.719 --> 00:01:13.196 It pushes against the dough from the inside, 00:01:13.220 --> 00:01:15.654 trying to escape through the cookie walls 00:01:15.678 --> 00:01:18.222 like Ridley Scott's chest-bursting alien. 00:01:19.111 --> 00:01:22.333 Your eggs may have been home to squirming salmonella bacteria. 00:01:22.357 --> 00:01:27.319 An estimated 142,000 Americans are infected this way each year. 00:01:27.343 --> 00:01:30.147 Though salmonella can live for weeks outside a living body 00:01:30.171 --> 00:01:31.764 and even survive freezing, 00:01:31.788 --> 00:01:35.385 136 degrees is too hot for them. 00:01:35.409 --> 00:01:38.093 When your dough reaches that temperature, they die off. 00:01:38.117 --> 00:01:41.179 You'll live to test your fate with a bite of raw dough 00:01:41.203 --> 00:01:42.888 you sneak from your next batch. 00:01:43.594 --> 00:01:47.069 At 144 degrees, changes begin in the proteins, 00:01:47.093 --> 00:01:49.489 which come mostly from the eggs in your dough. 00:01:49.513 --> 00:01:52.460 Eggs are composed of dozens of different kinds of proteins, 00:01:52.484 --> 00:01:55.016 each sensitive to a different temperature. 00:01:55.040 --> 00:01:56.780 In an egg fresh from the hen, 00:01:56.804 --> 00:01:59.731 these proteins look like coiled up balls of string. 00:01:59.755 --> 00:02:01.571 When they're exposed to heat energy, 00:02:01.595 --> 00:02:05.813 the protein strings unfold and get tangled up with their neighbors. 00:02:05.837 --> 00:02:07.290 This linked structure 00:02:07.314 --> 00:02:09.197 makes the runny egg nearly solid, 00:02:09.221 --> 00:02:11.824 giving substance to squishy dough. 00:02:11.848 --> 00:02:14.725 Water boils away at 212 degrees, 00:02:14.749 --> 00:02:16.474 so like mud baking in the sun, 00:02:16.498 --> 00:02:19.368 your cookie gets dried out and it stiffens. 00:02:19.392 --> 00:02:21.351 Cracks spread across its surface. 00:02:21.375 --> 00:02:24.112 The steam that was bubbling inside evaporates, 00:02:24.136 --> 00:02:27.776 leaving behind airy pockets that make the cookie light and flaky. 00:02:27.800 --> 00:02:29.848 Helping this along is your leavening agent, 00:02:29.872 --> 00:02:31.356 sodium bicarbonate, 00:02:31.380 --> 00:02:32.576 or baking soda. 00:02:32.600 --> 00:02:35.575 The sodium bicarbonate reacts with acids in the dough 00:02:35.599 --> 00:02:40.116 to create carbon dioxide gas, which makes airy pockets in your cookie. 00:02:40.140 --> 00:02:42.628 Now, it's nearly ready for a refreshing dunk 00:02:42.652 --> 00:02:44.667 in a cool glass of milk. 00:02:44.691 --> 00:02:47.496 One of science's tastiest reactions 00:02:47.520 --> 00:02:49.882 occurs at 310 degrees. 00:02:49.906 --> 00:02:52.497 This is the temperature for Maillard reactions. 00:02:52.521 --> 00:02:53.989 Maillard reactions result 00:02:54.013 --> 00:02:57.611 when proteins and sugars break down and rearrange themselves, 00:02:57.635 --> 00:02:59.134 forming ring-like structures, 00:02:59.158 --> 00:03:00.525 which reflect light in a way 00:03:00.549 --> 00:03:02.680 that gives foods like Thanksgiving turkey 00:03:02.704 --> 00:03:03.764 and hamburgers 00:03:03.788 --> 00:03:06.262 their distinctive, rich brown color. 00:03:06.867 --> 00:03:08.099 As this reaction occurs, 00:03:08.123 --> 00:03:11.009 it produces a range of flavor and aroma compounds, 00:03:11.033 --> 00:03:12.677 which also react with each other, 00:03:12.701 --> 00:03:15.698 forming even more complex tastes and smells. 00:03:16.508 --> 00:03:18.393 Caramelization is the last reaction 00:03:18.417 --> 00:03:20.370 to take place inside your cookie. 00:03:20.394 --> 00:03:22.185 Caramelization is what happens 00:03:22.209 --> 00:03:25.953 when sugar molecules break down under high heat, 00:03:25.977 --> 00:03:27.670 forming the sweet, nutty, 00:03:27.694 --> 00:03:32.013 and slightly bitter flavor compounds that define, well, caramel. 00:03:32.037 --> 00:03:35.515 And, in fact, if your recipe calls for a 350 degree oven, 00:03:35.539 --> 00:03:36.994 it'll never happen, 00:03:37.018 --> 00:03:40.931 since caramelization starts at 356 degrees. 00:03:40.955 --> 00:03:43.347 If your ideal cookie is barely browned, 00:03:43.371 --> 00:03:45.599 like a Northeasterner on a beach vacation, 00:03:45.623 --> 00:03:48.478 you could have set your oven to 310 degrees. 00:03:48.502 --> 00:03:50.761 If you like your cookies to have a nice tan, 00:03:50.785 --> 00:03:51.876 crank up the heat. 00:03:51.900 --> 00:03:55.698 Caramelization continues up to 390 degrees. 00:03:55.722 --> 00:03:56.913 And here's another trick: 00:03:56.937 --> 00:03:58.931 you don't need that kitchen timer; 00:03:58.955 --> 00:04:01.890 your nose is a sensitive scientific instrument. 00:04:01.914 --> 00:04:04.284 When you smell the nutty, toasty aromas 00:04:04.308 --> 00:04:07.031 of the Maillard reaction and caramelization, 00:04:07.055 --> 00:04:08.387 your cookies are ready. 00:04:08.411 --> 00:04:09.701 Grab your glass of milk, 00:04:09.725 --> 00:04:10.793 put your feet up, 00:04:10.817 --> 00:04:14.601 and reflect that science can be pretty sweet.