WEBVTT 00:00:07.042 --> 00:00:08.453 In a time-lapse video, 00:00:08.453 --> 00:00:10.707 it looks like a monster coming alive. 00:00:10.707 --> 00:00:13.619 For a moment, it sits there innocuously. 00:00:13.619 --> 00:00:16.196 Then, ripples move across its surface. 00:00:16.196 --> 00:00:17.630 It bulges outwards, 00:00:17.630 --> 00:00:19.587 bursting with weird boils. 00:00:19.587 --> 00:00:21.219 It triples in volume. 00:00:21.219 --> 00:00:23.462 Its color darkens ominously, 00:00:23.462 --> 00:00:24.796 and its surface hardens 00:00:24.796 --> 00:00:28.801 into an alien topography of peaks and craters. 00:00:28.801 --> 00:00:30.765 Then, the kitchen timer dings. 00:00:30.765 --> 00:00:32.141 Your cookie is ready. 00:00:32.141 --> 00:00:33.928 What happened inside that oven? 00:00:33.928 --> 00:00:35.841 Don't let the apron deceive you! 00:00:35.841 --> 00:00:38.229 Bakers are mad scientists. 00:00:38.229 --> 00:00:40.064 When you slide the pan into the oven, 00:00:40.064 --> 00:00:42.613 you're setting off a series of chemical reactions 00:00:42.613 --> 00:00:45.339 that transform one substance, dough, 00:00:45.339 --> 00:00:47.368 into another, cookies. 00:00:47.368 --> 00:00:50.313 When the dough reaches 92 degrees Fahrenheit, 00:00:50.313 --> 00:00:51.792 the butter inside melts, 00:00:51.792 --> 00:00:54.041 causing the dough to start spreading out. 00:00:54.041 --> 00:00:55.542 Butter is an emulsion, 00:00:55.542 --> 00:00:57.131 or mixture of two substances 00:00:57.131 --> 00:00:59.009 that don't want to stay together, 00:00:59.009 --> 00:01:01.038 in this case, water and fat, 00:01:01.038 --> 00:01:02.386 along with some dairy solids 00:01:02.386 --> 00:01:04.212 that help hold them together. 00:01:04.212 --> 00:01:05.172 As the butter melts, 00:01:05.172 --> 00:01:07.424 its trapped water is released. 00:01:07.424 --> 00:01:08.550 And as the cookie get hotter, 00:01:08.550 --> 00:01:10.719 the water expands into steam. 00:01:10.719 --> 00:01:13.220 It pushes against the dough from inside, 00:01:13.220 --> 00:01:15.678 trying to escape through the cookie walls 00:01:15.678 --> 00:01:18.640 like Ridley Scott's chest-bursting alien. 00:01:18.640 --> 00:01:20.193 Your eggs may have been home 00:01:20.193 --> 00:01:22.010 to squirming salmonella bacteria. 00:01:22.010 --> 00:01:24.771 An estimated 142,000 Americans 00:01:24.771 --> 00:01:27.343 are infected this way each year. 00:01:27.343 --> 00:01:28.902 Though salmonella can live for weeks 00:01:28.902 --> 00:01:30.171 outside a living body 00:01:30.171 --> 00:01:31.788 and even survive freezing, 00:01:31.788 --> 00:01:35.409 136 degrees is too hot for them. 00:01:35.409 --> 00:01:36.949 When your dough reaches that temperature, 00:01:36.949 --> 00:01:38.117 they die off. 00:01:38.117 --> 00:01:39.677 You'll live to test your fate 00:01:39.677 --> 00:01:41.203 with a bite of raw dough 00:01:41.203 --> 00:01:43.174 you sneak from your next batch. 00:01:43.174 --> 00:01:47.093 At 144 degrees, changes begin in the proteins, 00:01:47.093 --> 00:01:49.513 which come mostly from the eggs in your dough. 00:01:49.513 --> 00:01:50.983 Eggs are composed of dozens 00:01:50.983 --> 00:01:52.406 of different kinds of proteins, 00:01:52.406 --> 00:01:55.040 each sensitive to a different temperature. 00:01:55.040 --> 00:01:56.804 In an egg fresh from the hen, 00:01:56.804 --> 00:01:59.755 these proteins look like coiled up balls of string. 00:01:59.755 --> 00:02:01.595 When they're exposed to heat energy, 00:02:01.595 --> 00:02:03.588 the protein strings unfold 00:02:03.588 --> 00:02:05.837 and get tangled up with their neighbors. 00:02:05.837 --> 00:02:07.423 This linked structure makes 00:02:07.423 --> 00:02:09.221 the runny egg nearly solid, 00:02:09.221 --> 00:02:11.848 giving substance to squishy dough. 00:02:11.848 --> 00:02:14.749 Water boils away at 212 degrees, 00:02:14.749 --> 00:02:16.498 so like mud baking in the sun, 00:02:16.498 --> 00:02:19.392 your cookie gets dried out and it stiffens. 00:02:19.392 --> 00:02:21.375 Cracks spread across its surface. 00:02:21.375 --> 00:02:24.136 The steam that was bubbling inside evaporates, 00:02:24.136 --> 00:02:25.748 leaving behind airy pockets 00:02:25.748 --> 00:02:27.800 that make the cookie light and flaky. 00:02:27.800 --> 00:02:29.812 Helping this along is your leavening agent, 00:02:29.812 --> 00:02:31.380 sodium bicarbonate, 00:02:31.380 --> 00:02:32.600 or baking soda. 00:02:32.600 --> 00:02:34.104 The sodium bicarbonate reacts 00:02:34.104 --> 00:02:35.599 with acids in the dough 00:02:35.599 --> 00:02:37.713 to create carbon dioxide gas, 00:02:37.713 --> 00:02:40.014 which makes airy pockets in your cookie. 00:02:40.014 --> 00:02:42.652 Now, it's nearly ready for a refreshing dunk 00:02:42.652 --> 00:02:44.691 in a cool glass of milk. 00:02:44.691 --> 00:02:47.520 One of science's tastiest reactions 00:02:47.520 --> 00:02:49.906 occurs at 310 degrees. 00:02:49.906 --> 00:02:52.521 This is the temperature for Maillard reactions. 00:02:52.521 --> 00:02:54.013 Maillard reactions result 00:02:54.013 --> 00:02:56.026 when proteins and sugars break down 00:02:56.026 --> 00:02:57.635 and rearrange themselves, 00:02:57.635 --> 00:02:59.158 forming ring-like structures, 00:02:59.158 --> 00:03:00.549 which reflect light in a way 00:03:00.549 --> 00:03:02.704 that gives foods like Thanksgiving turkey 00:03:02.704 --> 00:03:03.788 and hamburgers 00:03:03.788 --> 00:03:06.498 their distinctive, rich brown color. 00:03:06.498 --> 00:03:08.123 As this reaction occurs, 00:03:08.123 --> 00:03:11.033 it produces a range of flavor and aroma compounds, 00:03:11.033 --> 00:03:12.701 which also react with each other, 00:03:12.701 --> 00:03:15.866 forming even more complex tastes and smells. 00:03:15.866 --> 00:03:18.141 Caramelization is the last reaction 00:03:18.141 --> 00:03:20.394 to take place inside your cookie. 00:03:20.394 --> 00:03:22.209 Caramelization is what happens 00:03:22.209 --> 00:03:25.977 when sugar molecules break down under high heat, 00:03:25.977 --> 00:03:27.694 forming the sweet, nutty, 00:03:27.694 --> 00:03:29.402 and slightly bitter flavor compounds 00:03:29.402 --> 00:03:32.037 that define, well, caramel. 00:03:32.037 --> 00:03:35.539 And in fact, if your recipe calls for a 350 degree oven, 00:03:35.539 --> 00:03:37.018 it'll never happen 00:03:37.018 --> 00:03:40.955 since caramelization starts at 356 degrees. 00:03:40.955 --> 00:03:43.371 If your ideal cookie is barely browned, 00:03:43.371 --> 00:03:45.623 like a Northeasterner on a beach vacation, 00:03:45.623 --> 00:03:48.502 you could have set your oven to 310 degrees. 00:03:48.502 --> 00:03:50.785 If you like your cookies to have a nice tan, 00:03:50.785 --> 00:03:51.900 crank up the heat. 00:03:51.900 --> 00:03:55.722 Caramelization continues up to 390 degrees. 00:03:55.722 --> 00:03:56.872 And here's another trick: 00:03:56.872 --> 00:03:58.955 you don't need that kitchen timer; 00:03:58.955 --> 00:04:01.914 your nose is a sensitive scientific instrument. 00:04:01.914 --> 00:04:04.308 When you smell the nutty, toasty aromas 00:04:04.308 --> 00:04:07.055 of the Maillard reaction and caramelization, 00:04:07.055 --> 00:04:08.411 your cookies are ready. 00:04:08.411 --> 00:04:09.725 Grab your glass of milk, 00:04:09.725 --> 00:04:10.816 put your feet up, 00:04:10.816 --> 00:04:14.778 and reflect that science can be pretty sweet.