WEBVTT 00:00:08.046 --> 00:00:10.696 This is a crystal of sugar. 00:00:10.696 --> 00:00:14.486 If you press on it, it will actually generate its own electricity. 00:00:14.486 --> 00:00:17.796 How can this simple crystal act like a tiny power source? 00:00:17.796 --> 00:00:20.386 Because sugar is piezoelectric. 00:00:20.386 --> 00:00:23.147 Piezoelectric materials turn mechanical stress, 00:00:23.147 --> 00:00:24.327 like pressure, 00:00:24.327 --> 00:00:25.190 sound waves, 00:00:25.190 --> 00:00:26.247 and other vibrations 00:00:26.247 --> 00:00:28.746 into electricity and vice versa. 00:00:28.746 --> 00:00:30.647 This odd phenomenon was first discovered 00:00:30.647 --> 00:00:34.966 by the physicist Pierre Curie and his brother Jacques in 1880. 00:00:34.966 --> 00:00:38.417 They discovered that if they compressed thin slices of certain crystals, 00:00:38.417 --> 00:00:43.018 positive and negative charges would appear on opposite faces. 00:00:43.018 --> 00:00:45.156 This difference in charge, or voltage, 00:00:45.156 --> 00:00:48.927 meant that the compressed crystal could drive current through a circuit, 00:00:48.927 --> 00:00:50.487 like a battery. 00:00:50.487 --> 00:00:52.718 And it worked the other way around, too. 00:00:52.718 --> 00:00:56.877 Running electricity through these crystals made them change shape. 00:00:56.877 --> 00:00:57.978 Both of these results, 00:00:57.978 --> 00:01:00.769 turning mechanical energy into electrical, 00:01:00.769 --> 00:01:03.157 and electrical energy into mechanical, 00:01:03.157 --> 00:01:04.699 were remarkable. 00:01:04.699 --> 00:01:08.146 But the discovery went uncelebrated for several decades. 00:01:08.146 --> 00:01:11.148 The first practical application was in sonar instruments 00:01:11.148 --> 00:01:14.648 used to detect German submarines during World War I. 00:01:14.648 --> 00:01:17.460 Piezoelectric quartz crystals in the sonar's transmitter 00:01:17.460 --> 00:01:21.459 vibrated when they were subjected to alternating voltage. 00:01:21.459 --> 00:01:23.949 That sent ultrasound waves through the water. 00:01:23.949 --> 00:01:27.179 Measuring how long it took these waves to bounce back from an object 00:01:27.179 --> 00:01:29.850 revealed how far away it was. 00:01:29.850 --> 00:01:31.528 For the opposite transformation, 00:01:31.528 --> 00:01:34.009 converting mechanical energy to electrical, 00:01:34.009 --> 00:01:36.829 consider the lights that turn on when you clap. 00:01:36.829 --> 00:01:39.539 Clapping your hands send sound vibrations through the air 00:01:39.539 --> 00:01:43.188 and causes the piezo element to bend back and forth. 00:01:43.188 --> 00:01:46.880 This creates a voltage that can drive enough current to light up the LEDs, 00:01:46.880 --> 00:01:50.420 though it's conventional sources of electricity that keep them on. 00:01:50.420 --> 00:01:53.629 So what makes a material piezoelectric? 00:01:53.629 --> 00:01:55.750 The answer depends on two factors: 00:01:55.750 --> 00:01:57.590 the materials atomic structure, 00:01:57.590 --> 00:02:00.970 and how electric charge is distributed within it. 00:02:00.970 --> 00:02:02.690 Many materials are crystalline, 00:02:02.690 --> 00:02:04.499 meaning they're made of atoms or ions 00:02:04.499 --> 00:02:07.630 arranged in an orderly three-dimensional pattern. 00:02:07.630 --> 00:02:10.270 That pattern has a building block called a unit cell 00:02:10.270 --> 00:02:12.730 that repeats over and over. 00:02:12.730 --> 00:02:15.561 In most non-piezoelectric crystalline materials, 00:02:15.561 --> 00:02:18.611 the atoms in their unit cells are distributed symmetrically 00:02:18.611 --> 00:02:20.474 around a central point. 00:02:20.474 --> 00:02:23.953 But some crystalline materials don't possess a center of symmetry 00:02:23.953 --> 00:02:27.102 making them candidates for piezoelectricity. 00:02:27.102 --> 00:02:28.515 Let's look at quartz, 00:02:28.515 --> 00:02:31.982 a piezoelectric material made of silicon and oxygen. 00:02:31.982 --> 00:02:36.721 The oxygens have a slight negative charge and silicons have a slight positive, 00:02:36.721 --> 00:02:38.252 creating a separation of charge, 00:02:38.252 --> 00:02:41.142 or a dipole along each bond. 00:02:41.142 --> 00:02:43.572 Normally, these dipoles cancel each other out, 00:02:43.572 --> 00:02:46.593 so there's no net separation of charge in the unit cell. 00:02:46.593 --> 00:02:49.574 But if a quartz crystal is squeezed along a certain direction, 00:02:49.574 --> 00:02:51.383 the atoms shift. 00:02:51.383 --> 00:02:54.134 Because of the resulting asymmetry in charge distribution, 00:02:54.134 --> 00:02:56.626 the dipoles no longer cancel each other out. 00:02:56.626 --> 00:03:00.457 The stretched cell ends up with a net negative charge on one side 00:03:00.457 --> 00:03:03.133 and a net positive on the other. 00:03:03.133 --> 00:03:06.283 This charge imbalance is repeated all the way through the material, 00:03:06.283 --> 00:03:09.937 and opposite charges collect on opposite faces of the crystal. 00:03:09.937 --> 00:03:13.874 This results in a voltage that can drive electricity through a circuit. 00:03:13.874 --> 00:03:16.914 Piezoelectric materials can have different structures. 00:03:16.914 --> 00:03:21.517 But what they all have in common is unit cells which lack a center of symmetry. 00:03:21.517 --> 00:03:24.354 And the stronger the compression on piezoelectric materials, 00:03:24.354 --> 00:03:26.744 the larger the voltage generated. 00:03:26.744 --> 00:03:29.964 Stretch the crystal, instead, and the voltage will switch, 00:03:29.964 --> 00:03:32.244 making current flow the other way. 00:03:32.244 --> 00:03:35.725 More materials are piezoelectric than you might think. 00:03:35.725 --> 00:03:36.664 DNA, 00:03:36.664 --> 00:03:37.395 bone, 00:03:37.395 --> 00:03:38.274 and silk 00:03:38.274 --> 00:03:42.426 all have this ability to turn mechanical energy into electrical. 00:03:42.426 --> 00:03:45.896 Scientists have created a variety of synthetic piezoelectric materials 00:03:45.896 --> 00:03:49.334 and found applications for them in everything from medical imaging 00:03:49.334 --> 00:03:51.536 to ink jet printers. 00:03:51.536 --> 00:03:54.845 Piezoelectricity is responsible for the rhythmic oscillations 00:03:54.845 --> 00:03:57.985 of the quartz crystals that keep watches running on time, 00:03:57.985 --> 00:03:59.846 the speakers of musical birthday cards, 00:03:59.846 --> 00:04:03.005 and the spark that ignites the gas in some barbecue grill lighters 00:04:03.005 --> 00:04:05.116 when you flick the switch. 00:04:05.116 --> 00:04:08.347 And piezoelectric devices may become even more common 00:04:08.347 --> 00:04:12.987 since electricity is in high demand and mechanical energy is abundant. 00:04:12.987 --> 00:04:15.936 There are already train stations that use passengers' footsteps 00:04:15.936 --> 00:04:18.478 to power the ticket gates and displays 00:04:18.478 --> 00:04:22.097 and a dance club where piezoelectricity helps power the lights. 00:04:22.097 --> 00:04:25.348 Could basketball players running back and forth power the scoreboard? 00:04:25.348 --> 00:04:28.668 Or might walking down the street charge your electronic devices? 00:04:28.668 --> 00:04:31.236 What's next for piezoelectricity?