WEBVTT 00:00:08.000 --> 00:00:10.000 Say two people are walking down the street 00:00:10.000 --> 00:00:11.000 and they bump into each other. 00:00:11.000 --> 00:00:14.000 They'll just shake it off and walk on. 00:00:14.000 --> 00:00:16.000 Sometimes that happens with molecules too. 00:00:16.000 --> 00:00:19.000 They just bounce off each other and that's that. 00:00:19.000 --> 00:00:21.000 But what if two people were to bump into each other, 00:00:21.000 --> 00:00:22.000 and during that collision, 00:00:22.000 --> 00:00:24.000 one person's arm got severed 00:00:24.000 --> 00:00:27.000 and reattached to the other person's face? 00:00:27.000 --> 00:00:29.000 Now that sounds really weird, 00:00:29.000 --> 00:00:31.000 but it's similar to one of the many ways 00:00:31.000 --> 00:00:33.000 that molecules can react with each other. 00:00:34.000 --> 00:00:36.000 Two molecules can join and become one. 00:00:36.000 --> 00:00:39.000 One can split apart and become two. 00:00:39.000 --> 00:00:40.000 Molecules can switch parts. 00:00:41.000 --> 00:00:43.000 All these changes are chemical reactions, 00:00:43.000 --> 00:00:45.000 and we can see them happening around us. 00:00:45.000 --> 00:00:48.000 For example, when fireworks explode, 00:00:48.000 --> 00:00:49.000 or iron rusts, 00:00:49.000 --> 00:00:50.000 or milk goes bad, 00:00:50.000 --> 00:00:51.000 or people are born, 00:00:51.000 --> 00:00:52.000 grow old, 00:00:52.000 --> 00:00:52.000 die, 00:00:52.000 --> 00:00:54.000 and then decompose. 00:00:54.000 --> 00:00:57.000 But chemical reactions don't just happen willy nilly! 00:00:57.000 --> 00:00:59.000 Everything has to be right. 00:00:59.000 --> 00:01:01.000 First, the molecules have to hit each other 00:01:01.000 --> 00:01:03.000 in the right orientation. 00:01:03.000 --> 00:01:05.000 And second, they have to hit each other hard enough, 00:01:05.000 --> 00:01:07.000 in other words, with enough energy. 00:01:08.000 --> 00:01:09.000 Now you're probably thinking 00:01:09.000 --> 00:01:11.000 that a reaction just happens in one direction and that's it. 00:01:12.000 --> 00:01:13.000 Sometimes that's true. 00:01:13.000 --> 00:01:15.000 For example, things can't unburn 00:01:15.000 --> 00:01:17.000 or unexplode. 00:01:17.000 --> 00:01:20.000 But most reactions can happen in both directions, 00:01:20.000 --> 00:01:22.000 forward and reverse. 00:01:23.000 --> 00:01:25.000 There's no reason that our face-arm guy 00:01:25.000 --> 00:01:27.000 can't bump into armless girl, 00:01:27.000 --> 00:01:30.000 reattaching that arm back to its original socket. 00:01:30.000 --> 00:01:31.000 Now let's zoom out a bit. 00:01:31.000 --> 00:01:32.000 Now let's say that you've got 00:01:32.000 --> 00:01:34.000 a thousand people on the street, 00:01:34.000 --> 00:01:35.000 and all of them start with their limbs 00:01:35.000 --> 00:01:37.000 normally attached. 00:01:37.000 --> 00:01:39.000 At the beginning, every collision is a chance 00:01:39.000 --> 00:01:43.000 for Person A to transfer an arm to Person B's face. 00:01:43.000 --> 00:01:44.000 And so at the beginning, 00:01:44.000 --> 00:01:45.000 more and more people end up 00:01:45.000 --> 00:01:48.000 with arms attached to their faces or arms missing. 00:01:48.000 --> 00:01:51.000 But as the number of people with arm-faces 00:01:51.000 --> 00:01:53.000 and missing arms grows, 00:01:53.000 --> 00:01:56.000 collisions between those people become more likely. 00:01:56.000 --> 00:01:58.000 And when they bump into each other, 00:01:58.000 --> 00:01:59.000 guess what? 00:01:59.000 --> 00:02:02.000 Normal-appendage people are reproduced. 00:02:02.000 --> 00:02:05.000 Now the number of limb transfers per second forward 00:02:05.000 --> 00:02:07.000 will start high and then fall, 00:02:07.000 --> 00:02:10.000 and the number of limb transfers per second backward 00:02:10.000 --> 00:02:12.000 will start at zero and then rise. 00:02:12.000 --> 00:02:13.000 Eventually they'll meet, 00:02:13.000 --> 00:02:14.000 they'll be the same. 00:02:14.000 --> 00:02:15.000 And when that happens, 00:02:15.000 --> 00:02:19.000 the number of people in each state stops changing, 00:02:19.000 --> 00:02:21.000 even though people are still bumping into each other 00:02:21.000 --> 00:02:23.000 and exchanging limbs. 00:02:23.000 --> 00:02:25.000 Now how many people do you think 00:02:25.000 --> 00:02:26.000 there are in each state? 00:02:26.000 --> 00:02:27.000 Half and half, right? 00:02:27.000 --> 00:02:29.000 No, well, maybe. 00:02:29.000 --> 00:02:30.000 It depends. 00:02:30.000 --> 00:02:32.000 It could be 50/50, 00:02:32.000 --> 00:02:33.000 but it could be 60/40 00:02:33.000 --> 00:02:34.000 or 15/85, 00:02:34.000 --> 00:02:35.000 or anything. 00:02:35.000 --> 00:02:38.000 We chemists have to get our little, gloved hands dirty 00:02:38.000 --> 00:02:41.000 - ah, well, we're in a lab so not really dirty - 00:02:41.000 --> 00:02:43.000 to figure out what the actually distribution 00:02:43.000 --> 00:02:44.000 of molecules is. 00:02:44.000 --> 00:02:46.000 Even though each of limb transfers 00:02:46.000 --> 00:02:49.000 is a pretty dramatic event for the people involved, 00:02:49.000 --> 00:02:50.000 if we zoom out, 00:02:50.000 --> 00:02:53.000 we see population numbers that don't change. 00:02:53.000 --> 00:02:55.000 We can this nirvana equilibrium, 00:02:55.000 --> 00:02:58.000 and it doesn't just happen with chemical reactions. 00:02:58.000 --> 00:02:59.000 Things like gene pools 00:02:59.000 --> 00:03:02.000 and highway traffic show the same pattern. 00:03:02.000 --> 00:03:04.000 It looks pretty still from 30,000 feet, 00:03:04.000 --> 00:03:06.000 but there is lots of crazy stuff 00:03:06.000 --> 00:03:07.000 happening on the ground, 00:03:07.000 --> 00:03:10.000 you just need to zoom in to see it.