0:00:08.000,0:00:10.000 Say two people are walking down the street 0:00:10.000,0:00:11.000 and they bump into each other. 0:00:11.000,0:00:14.000 They'll just shake it off and walk on. 0:00:14.000,0:00:16.000 Sometimes that happens with molecules too. 0:00:16.000,0:00:19.000 They just bounce off each other and that's that. 0:00:19.000,0:00:21.000 But what if two people were to bump into each other, 0:00:21.000,0:00:22.000 and during that collision, 0:00:22.000,0:00:24.000 one person's arm got severed 0:00:24.000,0:00:27.000 and reattached to the other person's face? 0:00:27.000,0:00:29.000 Now that sounds really weird, 0:00:29.000,0:00:31.000 but it's similar to one of the many ways 0:00:31.000,0:00:33.000 that molecules can react with each other. 0:00:34.000,0:00:36.000 Two molecules can join and become one. 0:00:36.000,0:00:39.000 One can split apart and become two. 0:00:39.000,0:00:40.000 Molecules can switch parts. 0:00:41.000,0:00:43.000 All these changes are chemical reactions, 0:00:43.000,0:00:45.000 and we can see them happening around us. 0:00:45.000,0:00:48.000 For example, when fireworks explode, 0:00:48.000,0:00:49.000 or iron rusts, 0:00:49.000,0:00:50.000 or milk goes bad, 0:00:50.000,0:00:51.000 or people are born, 0:00:51.000,0:00:52.000 grow old, 0:00:52.000,0:00:52.000 die, 0:00:52.000,0:00:54.000 and then decompose. 0:00:54.000,0:00:57.000 But chemical reactions don't just happen willy nilly! 0:00:57.000,0:00:59.000 Everything has to be right. 0:00:59.000,0:01:01.000 First, the molecules have to hit each other 0:01:01.000,0:01:03.000 in the right orientation. 0:01:03.000,0:01:05.000 And second, they have to hit each other hard enough, 0:01:05.000,0:01:07.000 in other words, with enough energy. 0:01:08.000,0:01:09.000 Now you're probably thinking 0:01:09.000,0:01:11.000 that a reaction just happens in one direction and that's it. 0:01:12.000,0:01:13.000 Sometimes that's true. 0:01:13.000,0:01:15.000 For example, things can't unburn 0:01:15.000,0:01:17.000 or unexplode. 0:01:17.000,0:01:20.000 But most reactions can happen in both directions, 0:01:20.000,0:01:22.000 forward and reverse. 0:01:23.000,0:01:25.000 There's no reason that our face-arm guy 0:01:25.000,0:01:27.000 can't bump into armless girl, 0:01:27.000,0:01:30.000 reattaching that arm back to its original socket. 0:01:30.000,0:01:31.000 Now let's zoom out a bit. 0:01:31.000,0:01:32.000 Now let's say that you've got 0:01:32.000,0:01:34.000 a thousand people on the street, 0:01:34.000,0:01:35.000 and all of them start with their limbs 0:01:35.000,0:01:37.000 normally attached. 0:01:37.000,0:01:39.000 At the beginning, every collision is a chance 0:01:39.000,0:01:43.000 for Person A to transfer an arm to Person B's face. 0:01:43.000,0:01:44.000 And so at the beginning, 0:01:44.000,0:01:45.000 more and more people end up 0:01:45.000,0:01:48.000 with arms attached to their faces or arms missing. 0:01:48.000,0:01:51.000 But as the number of people with arm-faces 0:01:51.000,0:01:53.000 and missing arms grows, 0:01:53.000,0:01:56.000 collisions between those people become more likely. 0:01:56.000,0:01:58.000 And when they bump into each other, 0:01:58.000,0:01:59.000 guess what? 0:01:59.000,0:02:02.000 Normal-appendage people are reproduced. 0:02:02.000,0:02:05.000 Now the number of limb transfers per second forward 0:02:05.000,0:02:07.000 will start high and then fall, 0:02:07.000,0:02:10.000 and the number of limb transfers per second backward 0:02:10.000,0:02:12.000 will start at zero and then rise. 0:02:12.000,0:02:13.000 Eventually they'll meet, 0:02:13.000,0:02:14.000 they'll be the same. 0:02:14.000,0:02:15.000 And when that happens, 0:02:15.000,0:02:19.000 the number of people in each state stops changing, 0:02:19.000,0:02:21.000 even though people are still bumping into each other 0:02:21.000,0:02:23.000 and exchanging limbs. 0:02:23.000,0:02:25.000 Now how many people do you think 0:02:25.000,0:02:26.000 there are in each state? 0:02:26.000,0:02:27.000 Half and half, right? 0:02:27.000,0:02:29.000 No, well, maybe. 0:02:29.000,0:02:30.000 It depends. 0:02:30.000,0:02:32.000 It could be 50/50, 0:02:32.000,0:02:33.000 but it could be 60/40 0:02:33.000,0:02:34.000 or 15/85, 0:02:34.000,0:02:35.000 or anything. 0:02:35.000,0:02:38.000 We chemists have to get our little, gloved hands dirty 0:02:38.000,0:02:41.000 - ah, well, we're in a lab so not really dirty - 0:02:41.000,0:02:43.000 to figure out what the actually distribution 0:02:43.000,0:02:44.000 of molecules is. 0:02:44.000,0:02:46.000 Even though each of limb transfers 0:02:46.000,0:02:49.000 is a pretty dramatic event for the people involved, 0:02:49.000,0:02:50.000 if we zoom out, 0:02:50.000,0:02:53.000 we see population numbers that don't change. 0:02:53.000,0:02:55.000 We can this nirvana equilibrium, 0:02:55.000,0:02:58.000 and it doesn't just happen with chemical reactions. 0:02:58.000,0:02:59.000 Things like gene pools 0:02:59.000,0:03:02.000 and highway traffic show the same pattern. 0:03:02.000,0:03:04.000 It looks pretty still from 30,000 feet, 0:03:04.000,0:03:06.000 but there is lots of crazy stuff 0:03:06.000,0:03:07.000 happening on the ground, 0:03:07.000,0:03:10.000 you just need to zoom in to see it.