WEBVTT 00:00:06.608 --> 00:00:08.670 Water is the liquid of life. 00:00:08.670 --> 00:00:09.392 We drink it, 00:00:09.392 --> 00:00:10.245 we bathe in it, 00:00:10.245 --> 00:00:10.864 we farm, 00:00:10.864 --> 00:00:11.196 cook, 00:00:11.196 --> 00:00:12.305 and clean with it. 00:00:12.305 --> 00:00:14.747 It's the most abundant molecule in our bodies. 00:00:14.747 --> 00:00:16.531 In fact, every life form we know of 00:00:16.531 --> 00:00:18.281 would die without it. 00:00:18.281 --> 00:00:20.377 But most importantly, without water, 00:00:20.377 --> 00:00:22.480 we wouldn't have 00:00:22.480 --> 00:00:23.426 iced tea. 00:00:23.426 --> 00:00:26.073 Mmmm, iced tea. 00:00:27.749 --> 00:00:29.871 Why do these ice cubes float? 00:00:29.871 --> 00:00:31.920 If these were cubes of solid argon 00:00:31.920 --> 00:00:33.824 in a cup of liquid argon, 00:00:33.824 --> 00:00:34.985 they would sink. 00:00:34.985 --> 00:00:37.637 And the same goes for most other substances. 00:00:37.637 --> 00:00:40.484 But solid water, a.k.a. ice, 00:00:40.484 --> 00:00:43.394 is somehow less dense than liquid water. 00:00:43.394 --> 00:00:45.222 How's that possible? 00:00:45.222 --> 00:00:46.927 You already know that every water molecule 00:00:46.927 --> 00:00:48.970 is made up of two hydrogen atoms 00:00:48.970 --> 00:00:51.314 bonded to one oxygen atom. 00:00:51.314 --> 00:00:52.682 Let's look at a few of the molecules 00:00:52.682 --> 00:00:54.173 in a drop of water, 00:00:54.173 --> 00:00:57.774 and let's say the temperature is 25 degrees Celcius. 00:00:57.774 --> 00:00:59.371 The molecules are bending, 00:00:59.371 --> 00:01:00.075 stretching, 00:01:00.075 --> 00:01:00.699 spinning, 00:01:00.699 --> 00:01:02.536 and moving through space. 00:01:02.536 --> 00:01:04.742 Now, let's lower the temperature, 00:01:04.742 --> 00:01:06.614 which will reduce the amount of kinetic energy 00:01:06.614 --> 00:01:08.782 each of these molecules has 00:01:08.782 --> 00:01:11.665 so they'll bend, stretch, spin, and move less. 00:01:11.665 --> 00:01:13.300 And that means that on average, 00:01:13.300 --> 00:01:15.461 they'll take up less space. 00:01:15.461 --> 00:01:17.092 Now, you'd think that as the liquid water 00:01:17.092 --> 00:01:18.533 starts to freeze, 00:01:18.533 --> 00:01:20.143 the molecules would just pack together 00:01:20.143 --> 00:01:21.732 more and more closely, 00:01:21.732 --> 00:01:23.743 but that's not what happens. 00:01:23.743 --> 00:01:25.087 Water has a special kind 00:01:25.087 --> 00:01:26.605 of interaction between molecules 00:01:26.605 --> 00:01:29.099 that most other substances don't have, 00:01:29.099 --> 00:01:30.983 and it's called a hydrogen bond. 00:01:30.983 --> 00:01:32.934 Now, remember that in a covalent bond 00:01:32.934 --> 00:01:35.187 two electrons are shared, 00:01:35.187 --> 00:01:36.399 usually unequally, 00:01:36.399 --> 00:01:37.609 between atoms. 00:01:37.609 --> 00:01:38.776 In a hydrogen bond, 00:01:38.776 --> 00:01:41.774 a hydrogen atom is shared, also unequally, 00:01:41.774 --> 00:01:43.390 between atoms. 00:01:43.390 --> 00:01:46.124 One hydrogen bond looks like this. 00:01:46.124 --> 00:01:47.878 Two look like this. 00:01:47.878 --> 00:01:48.784 Here's three 00:01:48.784 --> 00:01:49.725 and four 00:01:49.725 --> 00:01:50.715 and five, 00:01:50.715 --> 00:01:51.420 six, 00:01:51.420 --> 00:01:51.964 seven, 00:01:51.964 --> 00:01:52.439 eight, 00:01:52.439 --> 00:01:52.920 nine, 00:01:52.920 --> 00:01:53.231 ten, 00:01:53.231 --> 00:01:53.551 eleven, 00:01:53.551 --> 00:01:54.306 twelve, 00:01:54.306 --> 00:01:56.391 I could go on. 00:01:56.391 --> 00:01:57.776 In a single drop of water, 00:01:57.776 --> 00:02:00.146 hydrogen bonds form extended networks 00:02:00.146 --> 00:02:02.034 between hundreds, thousands, millions, 00:02:02.034 --> 00:02:04.201 billions, trillions of molecules, 00:02:04.201 --> 00:02:07.613 and these bonds are constantly breaking and reforming. 00:02:07.613 --> 00:02:09.816 Now, back to our water as it cools down. 00:02:09.816 --> 00:02:11.873 Above 4 degrees Celcius, 00:02:11.873 --> 00:02:13.524 the kinetic energy of the water molecules 00:02:13.524 --> 00:02:16.529 keeps their interactions with each other short. 00:02:16.529 --> 00:02:18.450 Hydrogen bonds form and break 00:02:18.450 --> 00:02:20.275 like high school relationships, 00:02:20.275 --> 00:02:22.588 that is to say, quickly. 00:02:22.588 --> 00:02:23.782 But below 4 degrees, 00:02:23.782 --> 00:02:25.713 the kinetic energy of the water molecules 00:02:25.713 --> 00:02:27.776 starts to fall below the energy 00:02:27.776 --> 00:02:29.671 of the hydrogen bonds. 00:02:29.671 --> 00:02:32.302 So, hydrogen bonds form much more frequently 00:02:32.302 --> 00:02:33.627 than they break 00:02:33.627 --> 00:02:35.479 and beautiful structures start to emerge 00:02:35.479 --> 00:02:37.113 from the chaos. 00:02:37.113 --> 00:02:39.452 This is what solid water, ice, 00:02:39.452 --> 00:02:41.946 looks like on the molecular level. 00:02:41.946 --> 00:02:44.303 Notice that the ordered, hexagonal structure 00:02:44.303 --> 00:02:47.003 is less dense than the disordered structure 00:02:47.003 --> 00:02:48.739 of liquid water. 00:02:48.739 --> 00:02:50.941 And you know that if an object is less dense 00:02:50.941 --> 00:02:52.370 than the fluid it's in, 00:02:52.370 --> 00:02:53.646 it will float. 00:02:53.646 --> 00:02:55.529 So, ice floats on water, 00:02:55.529 --> 00:02:56.727 so what? 00:02:56.727 --> 00:02:59.640 Well, let's consider a world without floating ice. 00:02:59.640 --> 00:03:00.999 The coldest part of the ocean 00:03:00.999 --> 00:03:03.237 would be the pitch-black ocean floor, 00:03:03.237 --> 00:03:05.162 once frozen, always frozen. 00:03:05.162 --> 00:03:06.569 Forget lobster rolls 00:03:06.569 --> 00:03:08.492 since crustaceans would lose their habitats, 00:03:08.492 --> 00:03:11.144 or sushi since kelp forests wouldn't grow. 00:03:11.144 --> 00:03:13.261 What would Canadian kids do in winter 00:03:13.261 --> 00:03:15.348 without pond hockey or ice fishing? 00:03:15.348 --> 00:03:17.134 And forget James Cameron's Oscar 00:03:17.134 --> 00:03:20.262 because the Titanic totally would have made it. 00:03:20.262 --> 00:03:22.088 Say goodbye to the white polar ice caps 00:03:22.088 --> 00:03:23.162 reflecting sunlight 00:03:23.162 --> 00:03:25.099 that would otherwise bake the planet. 00:03:25.099 --> 00:03:27.292 In fact, forget the oceans as we know them, 00:03:27.292 --> 00:03:29.692 which at over 70% of the Earth's surface area, 00:03:29.692 --> 00:03:32.110 regulate the atmosphere of the whole planet. 00:03:32.524 --> 00:03:33.862 But worst of all, 00:03:33.862 --> 00:03:37.246 there would be no iced tea. 00:03:37.246 --> 00:03:40.384 Mmmmm, iced tea.