1 00:00:06,608 --> 00:00:08,670 Water is the liquid of life. 2 00:00:08,670 --> 00:00:09,392 We drink it, 3 00:00:09,392 --> 00:00:10,245 we bathe in it, 4 00:00:10,245 --> 00:00:10,864 we farm, 5 00:00:10,864 --> 00:00:11,196 cook, 6 00:00:11,196 --> 00:00:12,305 and clean with it. 7 00:00:12,305 --> 00:00:14,747 It's the most abundant molecule in our bodies. 8 00:00:14,747 --> 00:00:16,531 In fact, every life form we know of 9 00:00:16,531 --> 00:00:18,281 would die without it. 10 00:00:18,281 --> 00:00:20,377 But most importantly, without water, 11 00:00:20,377 --> 00:00:22,480 we wouldn't have 12 00:00:22,480 --> 00:00:23,426 iced tea. 13 00:00:23,426 --> 00:00:26,073 Mmmm, iced tea. 14 00:00:27,749 --> 00:00:29,871 Why do these ice cubes float? 15 00:00:29,871 --> 00:00:31,920 If these were cubes of solid argon 16 00:00:31,920 --> 00:00:33,824 in a cup of liquid argon, 17 00:00:33,824 --> 00:00:34,985 they would sink. 18 00:00:34,985 --> 00:00:37,637 And the same goes for most other substances. 19 00:00:37,637 --> 00:00:40,484 But solid water, a.k.a. ice, 20 00:00:40,484 --> 00:00:43,394 is somehow less dense than liquid water. 21 00:00:43,394 --> 00:00:45,222 How's that possible? 22 00:00:45,222 --> 00:00:46,927 You already know that every water molecule 23 00:00:46,927 --> 00:00:48,970 is made up of two hydrogen atoms 24 00:00:48,970 --> 00:00:51,314 bonded to one oxygen atom. 25 00:00:51,314 --> 00:00:52,682 Let's look at a few of the molecules 26 00:00:52,682 --> 00:00:54,173 in a drop of water, 27 00:00:54,173 --> 00:00:57,774 and let's say the temperature is 25 degrees Celcius. 28 00:00:57,774 --> 00:00:59,371 The molecules are bending, 29 00:00:59,371 --> 00:01:00,075 stretching, 30 00:01:00,075 --> 00:01:00,699 spinning, 31 00:01:00,699 --> 00:01:02,536 and moving through space. 32 00:01:02,536 --> 00:01:04,742 Now, let's lower the temperature, 33 00:01:04,742 --> 00:01:06,614 which will reduce the amount of kinetic energy 34 00:01:06,614 --> 00:01:08,782 each of these molecules has 35 00:01:08,782 --> 00:01:11,665 so they'll bend, stretch, spin, and move less. 36 00:01:11,665 --> 00:01:13,300 And that means that on average, 37 00:01:13,300 --> 00:01:15,461 they'll take up less space. 38 00:01:15,461 --> 00:01:17,092 Now, you'd think that as the liquid water 39 00:01:17,092 --> 00:01:18,533 starts to freeze, 40 00:01:18,533 --> 00:01:20,143 the molecules would just pack together 41 00:01:20,143 --> 00:01:21,732 more and more closely, 42 00:01:21,732 --> 00:01:23,743 but that's not what happens. 43 00:01:23,743 --> 00:01:25,087 Water has a special kind 44 00:01:25,087 --> 00:01:26,605 of interaction between molecules 45 00:01:26,605 --> 00:01:29,099 that most other substances don't have, 46 00:01:29,099 --> 00:01:30,983 and it's called a hydrogen bond. 47 00:01:30,983 --> 00:01:32,934 Now, remember that in a covalent bond 48 00:01:32,934 --> 00:01:35,187 two electrons are shared, 49 00:01:35,187 --> 00:01:36,399 usually unequally, 50 00:01:36,399 --> 00:01:37,609 between atoms. 51 00:01:37,609 --> 00:01:38,776 In a hydrogen bond, 52 00:01:38,776 --> 00:01:41,774 a hydrogen atom is shared, also unequally, 53 00:01:41,774 --> 00:01:43,390 between atoms. 54 00:01:43,390 --> 00:01:46,124 One hydrogen bond looks like this. 55 00:01:46,124 --> 00:01:47,878 Two look like this. 56 00:01:47,878 --> 00:01:48,784 Here's three 57 00:01:48,784 --> 00:01:49,725 and four 58 00:01:49,725 --> 00:01:50,715 and five, 59 00:01:50,715 --> 00:01:51,420 six, 60 00:01:51,420 --> 00:01:51,964 seven, 61 00:01:51,964 --> 00:01:52,439 eight, 62 00:01:52,439 --> 00:01:52,920 nine, 63 00:01:52,920 --> 00:01:53,231 ten, 64 00:01:53,231 --> 00:01:53,551 eleven, 65 00:01:53,551 --> 00:01:54,306 twelve, 66 00:01:54,306 --> 00:01:56,391 I could go on. 67 00:01:56,391 --> 00:01:57,776 In a single drop of water, 68 00:01:57,776 --> 00:02:00,146 hydrogen bonds form extended networks 69 00:02:00,146 --> 00:02:02,034 between hundreds, thousands, millions, 70 00:02:02,034 --> 00:02:04,201 billions, trillions of molecules, 71 00:02:04,201 --> 00:02:07,613 and these bonds are constantly breaking and reforming. 72 00:02:07,613 --> 00:02:09,816 Now, back to our water as it cools down. 73 00:02:09,816 --> 00:02:11,873 Above 4 degrees Celcius, 74 00:02:11,873 --> 00:02:13,524 the kinetic energy of the water molecules 75 00:02:13,524 --> 00:02:16,529 keeps their interactions with each other short. 76 00:02:16,529 --> 00:02:18,450 Hydrogen bonds form and break 77 00:02:18,450 --> 00:02:20,275 like high school relationships, 78 00:02:20,275 --> 00:02:22,588 that is to say, quickly. 79 00:02:22,588 --> 00:02:23,782 But below 4 degrees, 80 00:02:23,782 --> 00:02:25,713 the kinetic energy of the water molecules 81 00:02:25,713 --> 00:02:27,776 starts to fall below the energy 82 00:02:27,776 --> 00:02:29,671 of the hydrogen bonds. 83 00:02:29,671 --> 00:02:32,302 So, hydrogen bonds form much more frequently 84 00:02:32,302 --> 00:02:33,627 than they break 85 00:02:33,627 --> 00:02:35,479 and beautiful structures start to emerge 86 00:02:35,479 --> 00:02:37,113 from the chaos. 87 00:02:37,113 --> 00:02:39,452 This is what solid water, ice, 88 00:02:39,452 --> 00:02:41,946 looks like on the molecular level. 89 00:02:41,946 --> 00:02:44,303 Notice that the ordered, hexagonal structure 90 00:02:44,303 --> 00:02:47,003 is less dense than the disordered structure 91 00:02:47,003 --> 00:02:48,739 of liquid water. 92 00:02:48,739 --> 00:02:50,941 And you know that if an object is less dense 93 00:02:50,941 --> 00:02:52,370 than the fluid it's in, 94 00:02:52,370 --> 00:02:53,646 it will float. 95 00:02:53,646 --> 00:02:55,529 So, ice floats on water, 96 00:02:55,529 --> 00:02:56,727 so what? 97 00:02:56,727 --> 00:02:59,640 Well, let's consider a world without floating ice. 98 00:02:59,640 --> 00:03:00,999 The coldest part of the ocean 99 00:03:00,999 --> 00:03:03,237 would be the pitch-black ocean floor, 100 00:03:03,237 --> 00:03:05,162 once frozen, always frozen. 101 00:03:05,162 --> 00:03:06,569 Forget lobster rolls 102 00:03:06,569 --> 00:03:08,492 since crustaceans would lose their habitats, 103 00:03:08,492 --> 00:03:11,144 or sushi since kelp forests wouldn't grow. 104 00:03:11,144 --> 00:03:13,261 What would Canadian kids do in winter 105 00:03:13,261 --> 00:03:15,348 without pond hockey or ice fishing? 106 00:03:15,348 --> 00:03:17,134 And forget James Cameron's Oscar 107 00:03:17,134 --> 00:03:20,262 because the Titanic totally would have made it. 108 00:03:20,262 --> 00:03:22,088 Say goodbye to the white polar ice caps 109 00:03:22,088 --> 00:03:23,162 reflecting sunlight 110 00:03:23,162 --> 00:03:25,099 that would otherwise bake the planet. 111 00:03:25,099 --> 00:03:27,292 In fact, forget the oceans as we know them, 112 00:03:27,292 --> 00:03:29,692 which at over 70% of the Earth's surface area, 113 00:03:29,692 --> 00:03:32,110 regulate the atmosphere of the whole planet. 114 00:03:32,524 --> 00:03:33,862 But worst of all, 115 00:03:33,862 --> 00:03:37,246 there would be no iced tea. 116 00:03:37,246 --> 00:03:40,384 Mmmmm, iced tea.