0:00:06.608,0:00:08.670 Water is the liquid of life. 0:00:08.670,0:00:09.392 We drink it, 0:00:09.392,0:00:10.245 we bathe in it, 0:00:10.245,0:00:10.864 we farm, 0:00:10.864,0:00:11.196 cook, 0:00:11.196,0:00:12.305 and clean with it. 0:00:12.305,0:00:14.747 It's the most abundant molecule in our bodies. 0:00:14.747,0:00:16.531 In fact, every life form we know of 0:00:16.531,0:00:18.281 would die without it. 0:00:18.281,0:00:20.377 But most importantly, without water, 0:00:20.377,0:00:22.480 we wouldn't have 0:00:22.480,0:00:23.426 iced tea. 0:00:23.426,0:00:26.073 Mmmm, iced tea. 0:00:27.749,0:00:29.871 Why do these ice cubes float? 0:00:29.871,0:00:31.920 If these were cubes of solid argon 0:00:31.920,0:00:33.824 in a cup of liquid argon, 0:00:33.824,0:00:34.985 they would sink. 0:00:34.985,0:00:37.637 And the same goes for most other substances. 0:00:37.637,0:00:40.484 But solid water, a.k.a. ice, 0:00:40.484,0:00:43.394 is somehow less dense than liquid water. 0:00:43.394,0:00:45.222 How's that possible? 0:00:45.222,0:00:46.927 You already know that every water molecule 0:00:46.927,0:00:48.970 is made up of two hydrogen atoms 0:00:48.970,0:00:51.314 bonded to one oxygen atom. 0:00:51.314,0:00:52.682 Let's look at a few of the molecules 0:00:52.682,0:00:54.173 in a drop of water, 0:00:54.173,0:00:57.774 and let's say the temperature is 25 degrees Celcius. 0:00:57.774,0:00:59.371 The molecules are bending, 0:00:59.371,0:01:00.075 stretching, 0:01:00.075,0:01:00.699 spinning, 0:01:00.699,0:01:02.536 and moving through space. 0:01:02.536,0:01:04.742 Now, let's lower the temperature, 0:01:04.742,0:01:06.614 which will reduce the amount of kinetic energy 0:01:06.614,0:01:08.782 each of these molecules has 0:01:08.782,0:01:11.665 so they'll bend, stretch, spin, and move less. 0:01:11.665,0:01:13.300 And that means that on average, 0:01:13.300,0:01:15.461 they'll take up less space. 0:01:15.461,0:01:17.092 Now, you'd think that as the liquid water 0:01:17.092,0:01:18.533 starts to freeze, 0:01:18.533,0:01:20.143 the molecules would just pack together 0:01:20.143,0:01:21.732 more and more closely, 0:01:21.732,0:01:23.743 but that's not what happens. 0:01:23.743,0:01:25.087 Water has a special kind 0:01:25.087,0:01:26.605 of interaction between molecules 0:01:26.605,0:01:29.099 that most other substances don't have, 0:01:29.099,0:01:30.983 and it's called a hydrogen bond. 0:01:30.983,0:01:32.934 Now, remember that in a covalent bond 0:01:32.934,0:01:35.187 two electrons are shared, 0:01:35.187,0:01:36.399 usually unequally, 0:01:36.399,0:01:37.609 between atoms. 0:01:37.609,0:01:38.776 In a hydrogen bond, 0:01:38.776,0:01:41.774 a hydrogen atom is shared, also unequally, 0:01:41.774,0:01:43.390 between atoms. 0:01:43.390,0:01:46.124 One hydrogen bond looks like this. 0:01:46.124,0:01:47.878 Two look like this. 0:01:47.878,0:01:48.784 Here's three 0:01:48.784,0:01:49.725 and four 0:01:49.725,0:01:50.715 and five, 0:01:50.715,0:01:51.420 six, 0:01:51.420,0:01:51.964 seven, 0:01:51.964,0:01:52.439 eight, 0:01:52.439,0:01:52.920 nine, 0:01:52.920,0:01:53.231 ten, 0:01:53.231,0:01:53.551 eleven, 0:01:53.551,0:01:54.306 twelve, 0:01:54.306,0:01:56.391 I could go on. 0:01:56.391,0:01:57.776 In a single drop of water, 0:01:57.776,0:02:00.146 hydrogen bonds form extended networks 0:02:00.146,0:02:02.034 between hundreds, thousands, millions, 0:02:02.034,0:02:04.201 billions, trillions of molecules, 0:02:04.201,0:02:07.613 and these bonds are constantly breaking and reforming. 0:02:07.613,0:02:09.816 Now, back to our water as it cools down. 0:02:09.816,0:02:11.873 Above 4 degrees Celcius, 0:02:11.873,0:02:13.524 the kinetic energy of the water molecules 0:02:13.524,0:02:16.529 keeps their interactions with each other short. 0:02:16.529,0:02:18.450 Hydrogen bonds form and break 0:02:18.450,0:02:20.275 like high school relationships, 0:02:20.275,0:02:22.588 that is to say, quickly. 0:02:22.588,0:02:23.782 But below 4 degrees, 0:02:23.782,0:02:25.713 the kinetic energy of the water molecules 0:02:25.713,0:02:27.776 starts to fall below the energy 0:02:27.776,0:02:29.671 of the hydrogen bonds. 0:02:29.671,0:02:32.302 So, hydrogen bonds form much more frequently 0:02:32.302,0:02:33.627 than they break 0:02:33.627,0:02:35.479 and beautiful structures start to emerge 0:02:35.479,0:02:37.113 from the chaos. 0:02:37.113,0:02:39.452 This is what solid water, ice, 0:02:39.452,0:02:41.946 looks like on the molecular level. 0:02:41.946,0:02:44.303 Notice that the ordered, hexagonal structure 0:02:44.303,0:02:47.003 is less dense than the disordered structure 0:02:47.003,0:02:48.739 of liquid water. 0:02:48.739,0:02:50.941 And you know that if an object is less dense 0:02:50.941,0:02:52.370 than the fluid it's in, 0:02:52.370,0:02:53.646 it will float. 0:02:53.646,0:02:55.529 So, ice floats on water, 0:02:55.529,0:02:56.727 so what? 0:02:56.727,0:02:59.640 Well, let's consider a world without floating ice. 0:02:59.640,0:03:00.999 The coldest part of the ocean 0:03:00.999,0:03:03.237 would be the pitch-black ocean floor, 0:03:03.237,0:03:05.162 once frozen, always frozen. 0:03:05.162,0:03:06.569 Forget lobster rolls 0:03:06.569,0:03:08.492 since crustaceans would lose their habitats, 0:03:08.492,0:03:11.144 or sushi since kelp forests wouldn't grow. 0:03:11.144,0:03:13.261 What would Canadian kids do in winter 0:03:13.261,0:03:15.348 without pond hockey or ice fishing? 0:03:15.348,0:03:17.134 And forget James Cameron's Oscar 0:03:17.134,0:03:20.262 because the Titanic totally would have made it. 0:03:20.262,0:03:22.088 Say goodbye to the white polar ice caps 0:03:22.088,0:03:23.162 reflecting sunlight 0:03:23.162,0:03:25.099 that would otherwise bake the planet. 0:03:25.099,0:03:27.292 In fact, forget the oceans as we know them, 0:03:27.292,0:03:29.692 which at over 70% of the Earth's surface area, 0:03:29.692,0:03:32.110 regulate the atmosphere of the whole planet. 0:03:32.524,0:03:33.862 But worst of all, 0:03:33.862,0:03:37.246 there would be no iced tea. 0:03:37.246,0:03:40.384 Mmmmm, iced tea.